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- - -------- - - - - - - -- - - - - - - -------- - - - - - - - ---------------- - - Liquid - - - - === - --- -- - = T , P , {xi) -: I=:= ------------------------ - - - ---- - - -----

Figure 21-1. The KEEP ALIVE block and its configuration panel Notice that the configuration panel is blank! There are no settings to configure with the KEEP ALIVE block.

First cylinder (1201-1305, default 1201): 1201

Thus, the fugacity of species i (in both the liquid and vapor phases) is equal to the partial pressure of species i in the vapor phase Its value increases from zero at infinite dilution (xi = yi -+ 0) to Pisat for pure species i This is illustrated by the data of Table 121 for the methyl ethyl ketone(l)/toluene(2) system at 32315 K (50 C)' The first three columns list a set of experimental P-xl-yl data and columns 4 and 5 show:

8 Instead of designating a megabyte value for the size of this partition, we enter the last cylinder number, thus taking up the remainder of the disk Accept the default suggested for the last cylinder On our sample system, this value is 1305 Type 1305

Table 121 VLE Data for Methyl Ethyl Ketone(l)TToluene(2) at 32315 K (50 C)

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Last cylinder or +size or +sizeM or +sizeK (1201-1305, default 1305): 1305

The fugacities are plotted in Fig 122 as solid lines The straight dashed lines represent Eq (1 180), the Lewis/Randall rule, which expresses the composition dependence of the constituent fugacities in an ideal solution:

9 By default, fdisk creates ext2-type partitions (ie, 0x83) But we want to create a partition of type Linux LVM Change the partition type from the default Linux (0x83) to the Linux LVM type To do this, we use the t (change partition type) command Type t

(1180)

'M Diaz Peiia, A Crespo Colin, and A Compostizo, J Chem Thermodyn, vol 10, pp 337-341, 1978

7:

Figure 122 Fugacities for methyl ethyl ketone(l)/toluene(2)at 32315 K (50 C)The dashed lines represent the Lewis/Randall rule

10 Enter the partition number whose type you want to change We want to change the type for the /dev/hda3 partition that was just created, so type 3 when prompted for a partition number

Although derived from a particular set of data, Fig 122 illustrates the general characteristics of the and vs x l relationships for a binary liquid solution at constant T The equilibrium pressure P varies with composition, but its influence on and is negligible Thus a plot at constant T and P would look the same, as indicated in Fig 123 for species i (i = 1,2) in a binary solution at constant T and P

Partition number (1-4): 3

Here s how it works: During the execution of your program, if at any time a KEEP ALIVE block is executed, the Sleep timer resets to its initial starting time. So, if you configured your Brick for a 5-minute Sleep timer and 1 minute into the program a KEEP ALIVE block is encountered, the Sleep timer will reset to 5 minutes. Now, to make this useful, you ll probably need to place the KEEP ALIVE block in a location where it will frequently be executed. The best location is a LOOP block that will occasionally (or continually) run the blocks inside it, including the KEEP ALIVE block. This is one method for continually resetting the Sleep timer. An example is shown in Figure 21-2.

The three most common measures of composition are mass fraction, mole fraction, and molar concentration Mass or mole fraction is defined as the ratio of the mass or number of moles of a particular chemical species in a mixture or solution to the total mass or number of moles of the mixture or solution:

11 Enter the partition type for Linux LVM Type 8e at the prompt:

Molar concentration is defined as the ratio of the mole fraction of a particular chemical species in a mixture or solution to its molar volume:

Command (m for help): p Disk /dev/sda: 107 GB, 10737418240 bytes 255 heads, 63 sectors/track, 1305 cylinders Units = cylinders of 16065 * 512 = 8225280 bytes Disk identifier: 0x00005158 Device Boot Start End Blocks Id System /dev/sda1 * 1 25 200781 83 Linux /dev/sda2 26 1200 9438187+ 8e Linux LVM /dev/sda3 1201 1305 843412+ 8e Linux LVM

This quantity has units of moles of i per unit volume For flow processes convenience suggests its expression as a ratio of rates Multiplying and dividing by molar flow rate ri gives:

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