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On the basis of this result, Duhem's theorem is stated as follows: For any closed system formed initially from given masses of prescribed chemical species, the equilibrium state is completely determined when any two independent variables are fixed The two independent variables subject to specification may in general be either intensive or extensive However, the number of independent intensive variables is given by the phase rule Thus when F = 1, at least one of the two variables must be extensive, and when F = 0, both must be extensive

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Here we will assign the physical volume created earlier to a volume group (VG) 1 First use the vgdisplay command to view the current volume groups that might exist on your system Type

The lower dashed line in Fig 123, representing the LewisRandall mle, is characteristic of ideal-solution behavior It provides the simplest possible model for the composition dependence of fl, representing a standard to which actual behavior may be compared Indeed, the activity coefficient as defined by Eq (1187) formalizes this comparison:

[root@fedora-serverA ~]# vgdisplay --- Volume group --VG Name VolGroup00 System ID Format lvm2 (Output truncated) VG Size 900 GB PE Size 3200 MB Total PE 288 Alloc PE / Size 287 / 897 GB Free PE / Size 1 / 3200 MB VG UUID T4153B-80Zu-KQPs-sWwt-X5sg-0G78-EAiEp0

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Thus the activity coefficient of a species in solution is the ratio of its actual fugacity to the value given by the LewisRandall rule at the same T, P, and composition For the calculation

7:

f^jd are eliminated in favor of measurable quantities:'

From the preceding output, we can tell that The volume group name (VG Name) is VolGroup00 The current size of the VG is 9GB (this should increase by the time we are done) The physical extent size is 32MB, and there are a total of 288 PEs There is only one physical extent that is free in the VG It is equivalent to 32MB of space 2 Assign the PV to the volume group using the vgextend command The syntax for the command is

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This is a restatement of Eq (105), modified Raoult's law, and is adequate for present purposes, allowing easy calculation of activity coefficients from experimental low-pressure VLE data Values from this equation appear in the last two columns of Table 121 The solid lines in both Figs 122 and 123, representingexperimental values of become tangent to the LewisIRandall-rule lines at xi = 1 This is a consequence of the GibbsIDuhem equation, as is shown later In the other limit, xi + 0, becomes zero Thus, the ratio j / x i is indeterminate in this limit, and application of 1'Hbpital's rule yields:

This happens frequently when the Sleep timer is set to 2 minutes or 5 minutes, so double-check this before running a program, and be certain to set the Sleep timer to a setting that is longer than you expect the program to run To close out this chapter, the last item I want to mention about the KEEP ALIVE block is that it does have an output data plug in its data hub This data plug will only supply a Number data type, and that number will always be the Sleep timer default value in milliseconds (1,000 milliseconds = 1 second) You might not find this data plug very useful, but it could be used as input to a COMPARE block that looks to see which is greater a value from one of the Brick s three internal timers or the default Sleep timer value.

[root@fedora-serverA ~]# vgextend VolGroup00 /dev/sda3 Volume group "VolGroup00" successfully extended

Equation (122) defines Henry's constant X i , as the limiting slope of the ff-vs-xi curve at xi = 0 As shown by Fig 113, this is the slope of a line drawn tangent to the curve at x; = 0 The equation of this tangent line expresses Henry's law:

[root@fedora-serverA ~]# vgdisplay --- Volume group --VG Name VolGroup00 (Output truncated) Act PV 2 VG Size 978 GB PE Size 3200 MB Total PE 313 Alloc PE / Size 287 / 897 GB Free PE / Size 26 / 83200 MB

It applies in the limit as xi -+ 0, and must also be of approximate validity for small values of xi Henry's law as given by Eq (104) follows immediately from this equation when = yi P , ie, when has its ideal-gas value Henry's law is related to the LewisIRandall rule through the GibbsIDuhem equation Writing Eq (1114) for a binary solution and replacing Mi by Gi = pi gives:

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