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13 Once you are satisfied with your changes, commit or write the changes you ve made to the disk s partition table using the w (write table to disk) command:

where rii is molar flow rate of species i , and q is volumetric flow rate The molar mass of a mixture or solution is, by definition, the mole-fraction-weighted sum of the molar masses of all species present:

15 When you are back at the shell prompt, reboot the system to allow the Linux kernel to properly recognize the new partition table Type

The phase rule for nonreacting systems, presented without proof in Sec 27, results from application of a rule of algebra Thus, the number of variables that may be independently fixed in a system at equilibrium is the difference between the total number of variables that characterize the intensive state of the system and the number of independent equations that can be written connecting the variables The intensive state of a P V T system containing N chemical species and n phases in equilibrium is characterized by the intensive variables, temperature T, pressure P, and

Next, create the physical volume itself 1 After the system comes back up from the reboot, log back in as the superuser 2 First let s view the current physical volumes defined on the system Type

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N - 1 mole fractions1 for each phase These are the phase-rule variables, and their number is 2 ( N - l)(n) The masses of the phases are not phase-rule variables, because they have no influence on the intensive state of the system As will become clear later in this chapter, an independent phase-equilibrium equation may be written connecting intensive variables for each of the N species for each pair of phases present Thus, the number of independent phase-equilibrium equations is ( n - 1)(N) The difference between the number of phase-rule variables and the number of independent equations connecting them is the number of variables that may be independently fixed Called the degrees of freedom of the system F, the number is:

[root@fedora-serverA ~]# pvdisplay --- Physical volume ---

Upon reduction, this becomes the phase rule:

PV Name /dev/sda2 VG Name VolGroup00 PV Size 900 GB / not usable 100300 KB (OUTPUT TRUNCATED)

Duhem's theorem is another rule, similar to the phase rule, but less celebrated It applies to closed systems at equilibrium for which the extensive state as well as the intensive state of the system is fixed The state of such a system is said to be completely determined, and is characterized not only by the 2 ( N - 1)n intensive phase-rule variables but also by the n extensive variables represented by the masses (or mole numbers) of the phases Thus the total number of variables is:

Figure 21-2 Put a KEEP ALIVE inside a LOOP, and you can repeatedly reset the Sleep timer In this simple program, the bot will spin around a few times, say Hello , and then do it again and again and again if the Touch sensor button is ever pressed, the SWITCH block will execute the KEEP ALIVE block, which resets the Sleep timer If the button is never pressed, the bot will eventually turn off when the default Sleep timer value has been reached This is important: always check the Sleep timer setting on your Brick before running a program Once the time has expired, the program will stop.

Take note of the physical volume name field (PV Name) 3 Use the pvcreate command to initialize the partition we created earlier as a physical volume Type

If the system is closed and formed from specified amounts of the chemical species present, then a material-balance equation can be written for each of the N chemical species These in addition to the ( n - l ) N phase-equilibrium equations provide a total number of independent equations equal to:

The difference between the number of variables and the number of equations is therefore:

[root@fedora-serverA ~]# pvdisplay --- Physical volume --PV Name /dev/sda2 VG Name VolGroup00 (OUTPUT TRUNCATED) --- NEW Physical volume --PV Name /dev/sda3 VG Name PV Size 82364 MB (OUTPUT TRUNCATED)

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